Abstract: Si/(Yb1-xYx)2Si2O7/LaMgAl11O19(x=0, 0.5) thermal/environmental barrier coatings (T/EBCs) were prepared by plasma sprayingmethod on the surface of SiC fiber reinforced SiC ceramic composites (SiCf/SiC-CMCs). The thermal cycle performance and water-oxygen corrosion resistance at 1 300 ℃ of T/EBCs systems with different components were investigated by means of SEM, EDS and XRD. And failure mechanisms of the thermal cycle and water-oxygen corrosion were further discussed. The results indicate that the thermal cycle life of Si/Yb2Si2O7/LMA coating system is 403 cycles and water-oxygen corrosion resistance is 50 h. The thermal cycle life of Si/YbYSi2O7/LMA system decreases to 277 cycles, while the water-oxygen corrosion resistance increases to 80 h. The larger thermal mismatch stress and the formation of Al-containing compounds or solid solutions between YbYSi2O7 and LMA are the main factors that reduce the thermal cycle life of Si/YbYSi2O7/LMA. The less oxide impurities in the YbYSi2O7-EBC layer reduce the probability of reaction with water to generate volatile substances, and improve the water-oxygen corrosion resistance of Si/YbYSi2O7/LMA.
Key words: SiCf/SiC-CMCs, thermal/environmental barrier coating, thermal barrier coating, environmental barrier coating, thermal cycle, high temperature water-oxygen corrosion, Yb2Si2O7, YbYSi2O7
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